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Agotime Ziope formerly Adaklu Anyibe is one of the twenty five (25) Municipalities and Districts in the Volta Region of Ghana and was established by Legislative Instrument (L.I) 2080. The Administrative Capital of the District is Kpetoe. Agotime-Ziope District is bordered by the Republic of Togo to the East; Akatsi North and Central Tongu Districts to the South and the Adaklu District to the West and North. The District covers a total land area of about Six Hundred and Thirty- Seven kilometres square (637km2).
The population of the municipality according to 2010 population and housing census stands at 34,456 with 16,788 males and 17,668 females.